1. Insert a “Drawing canvas” (DC for short) to your Word document:

2. Adjust the size of the DC as necessary:

3. Right click the DC, click “Format Drawing Canvas...”, and then set its fill color to white.
4. Insert the picture into the DC or using Cut/Paste to move an existing picture into the DC:

5. Add the annotating text by insert callouts into the DC:

6. Change the font of the annotating text to “Verdana” will get better result.